Coherent band excitations in CePd<sub>3</sub>: A comparison of neutron scattering and ab initio theory.
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Abstract | :
In common with many strongly correlated electron systems, intermediate valence compounds are believed to display a crossover from a high-temperature regime of incoherently fluctuating local moments to a low-temperature regime of coherent hybridized bands. We show that inelastic neutron scattering measurements of the dynamic magnetic susceptibility of CePd3 provides a benchmark for ab initio calculations based on dynamical mean field theory. The magnetic response is strongly momentum dependent thanks to the formation of coherent f-electron bands at low temperature, with an amplitude that is strongly enhanced by local particle-hole interactions. The agreement between experiment and theory shows that we have a robust first-principles understanding of the temperature dependence of f-electron coherence. |
Year of Publication | :
2018
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Journal | :
Science (New York, N.Y.)
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Volume | :
359
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Issue | :
6372
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Number of Pages | :
186-191
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Date Published | :
2018
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ISSN Number | :
0036-8075
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DOI | :
10.1126/science.aan0593
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Short Title | :
Science
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