Synthesis and crystal structure of bis-(μ-2-methyl-benzene-thiol-ato-κ<sup>2</sup><i>S</i>:<i>S</i>)bis- meth-yl(2-methyl-benzene-thiol-ato-κ<i>S</i>)indium(III) .
| Author | |
|---|---|
| Abstract | :
The dinuclear title compound, [In(CH)(CHS)] or [Me(2-MeCHS)In-μ-(2-MeCHS)InMe(2-MeCHS)], was prepared from the 1:2 reaction of MeIn and 2-MeCHSH in toluene. Its crystal structure exhibits a four-membered InS ring core bridging (2-MeCHS) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the axis inter-molecular In⋯S contacts. The In atoms are then in distorted trigonal-bipyramidal CS bonding environments. |
| Year of Publication | :
2017
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| Journal | :
Acta crystallographica. Section E, Crystallographic communications
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| Volume | :
73
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| Issue | :
Pt 4
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| Number of Pages | :
481-483
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| Date Published | :
2017
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| DOI | :
10.1107/S2056989017003498
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| Short Title | :
Acta Crystallogr E Crystallogr Commun
|
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